R-(-)-1,1'-BINAPHTHYL-2,2'-DIYL
HYDROGENPHOSPHATE |
PRODUCT
IDENTIFICATION
|
CAS
NO. |
39648-67-4 |
|
EINECS
NO. |
|
FORMULA |
C20H13O4P |
MOL
WT. |
348.29 |
H.S.
CODE
|
|
TOXICITY
|
|
DERIVATION
|
|
SYNONYMS |
R-(-)-1,1[-Binaphthyl-2,2]-diyl hydrogenphosphate; |
(R)-(-)-1,1'-Binaphthalene-2,2'-diyl hydrogen
phosphate; R-(-)-BNP Acid; (R)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-oxide;
|
CLASSIFICATION
|
|
PHYSICAL
AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
off-white
powder
|
MELTING
POINT |
>300
C
|
BOILING
POINT |
|
SPECIFIC
GRAVITY |
|
SOLUBILITY
IN WATER |
|
pH |
|
VAPOR
DENSITY |
|
AUTOIGNITION
|
|
NFPA
RATINGS
|
Health: 1 Flammability: 0 Reactivity: 0 |
REFRACTIVE
INDEX
|
|
FLASH
POINT |
|
STABILITY |
Stable
under ordinary conditions. |
GENERAL
DESCRIPTION
|
An effective chiral resolving agents for racemic amines. Its complexes with
palladium and are rhodium are useful catalysts in asymmetric hydrocarboxylations
and cycloadditions. |
SALES
SPECIFICATION |
APPEARANCE
|
off-white
powder
|
CHEMICAL
PURITY
|
98.0%
min |
OPTICAL
PUIRTY
|
98.0%
min e.e. |
TRANSPORTATION |
PACKING |
|
HAZARD
CLASS |
|
UN
NO. |
|
OTHER
INFORMATION |
Hazard Symbols: XI, Risk Phrases: 36/37/38,
Safety Phrases: 26-36 Optical
Rotation: -605°
(C=1, MeOH) |
|